Synthesis and heterodimetallic complexes of lateral macrobicyclic cryptands
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1232-1234
- https://doi.org/10.1039/c39860001232
Abstract
The macrobicyclic molecules (1a–c) have been synthesized; they are heteroditopic ligands combining a ‘soft’ and a ‘hard’ binding subunit, which form lateral dinuclear cryptates such as [Rh+–CO, Mn+⊂(1a–c)] by selective complexation to a given site.Keywords
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