-Representability Problem: Conditions on Geminals
- 5 July 1969
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 183 (1) , 129-141
- https://doi.org/10.1103/physrev.183.129
Abstract
The -representability problem is approached by considering geminal product expansions of symmetric and antisymmetric functions. The -completeness problem, i.e., the problem of determining when a set of geminals is a suitable basis for expanding symmetric or antisymmetric -particle functions, is considered. New necessary conditions are given for both -completeness and -representability. In some cases, one can also obtain sufficient conditions; examples of such cases are discussed. The circumstances under which a density matrix can be derived from two or more different functions are also treated. Finally, extensions to higher order are also mentioned.
Keywords
This publication has 5 references indexed in Scilit:
- -Representability Problem for an Odd Number of FermionsPhysical Review B, 1968
- Reduced-Density-Matrix Theory: The 2-Matrix of Four-Electron SystemsPhysical Review B, 1967
- Formulation of the Many-Body Problem for Composite ParticlesJournal of Mathematical Physics, 1963
- Structure of Fermion Density MatricesReviews of Modern Physics, 1963
- Eigenvalues of Density MatricesPhysical Review B, 1961