The first stereospecific catalytic hydrogenation with a polymer supported optically active rhodium complex
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 1098-1099
- https://doi.org/10.1039/c39860001098
Abstract
Optical yields up to 100% are obtained in the heterogeneous hydrogenation of α-(acetylamino)cinnamic acid and its methyl ester in the presence of rhodium complexes of 3,4-(R,R)-bis(diphenylphosphino)pyrrolidine, bound covalently to silica.Keywords
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