Hydroxyalkylation of Diethylvinylphosphonate in the Presence of DABCO
- 1 March 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (5) , 659-663
- https://doi.org/10.1080/00397919008052307
Abstract
Diethyl vinylphosphonate can be coupled with aldehydes in the presence of DABCO as a catalyst to give high yields of the corresponding α-hydroxyalkyl phosphonates.Keywords
This publication has 8 references indexed in Scilit:
- A General Synthesis of α-Methylene-β-HydroxyalkanonesSynthetic Communications, 1987
- Asymmetric Synthesis of 2-Substituted Acrylate EstersSynthetic Communications, 1987
- Hydroxyalkylation de la methylvinylcetone et de l'acrylonitrile en presence de diaza-1,4 bicyclo [2.2.2] octaneTetrahedron Letters, 1986
- Synthesis of potentially allergenic chiral α-(hydroxyalkyl) acrylates.Tetrahedron Letters, 1984
- Synthesis of 2-(1-Hydroxyalkyl)acrylonitriles by the Cocatalysis of a Base and an AcidSynthetic Communications, 1984
- Wittig-Horner Reaction in Heterogenous Media: V1. An Efficient Synthesis of Alkene-Phosphonates and αL-Hydroxymethyl-α-Vinyl Phosphonate in Water in the Presence of Potassium CarbonateSynthetic Communications, 1984
- 1,4‐Diazobicyclo[2.2.2]octane‐catalyzed coupling of aldehydes and activated double bonds. Part 3. A short ans practical synthesis of mikanecic acid (4‐vinyl‐1‐cyclohexene‐1,4‐dicarboxylic acid)Helvetica Chimica Acta, 1984
- Preparation of 2‐(1‐Hydroxyalkyl)acrylic Esters; Simple Three‐Step Synthesis of Mikanecic AcidAngewandte Chemie International Edition in English, 1983