Selenoaldehydes formed by 1,2-elimination and trapped as Diels–Alder adducts
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1152-1154
- https://doi.org/10.1039/c39860001152
Abstract
Various selenenyl derivatives, RO2C·CH2SeX, underwent elimination with triethylamine to form selenoaldehydes, RO2C·CHSe, which were trapped in situ as cycloadducts with conjugated dienes; the adduct of ethyl selenoxoacetate and anthracene dissociated upon heating thereby allowing transfer of the selenoaldehyde to 2,3-dimethylbuta-1,3-diene.Keywords
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