Stablization by a strongly acidic medium of trivalent copper tetra-aza macrocyclic complexes
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 806-808
- https://doi.org/10.1039/c39840000806
Abstract
The otherwise unstable CuIII complexed with tetra-aza macrocycles (1)–(3) are stabilized in strongly acidic solutions; the CuIII complex with the diene macrocycle (1) shows a grater stability (in 10 M HClO4)than the corresponding NiIII complex, an inversion of the normally observed trend.Keywords
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