Synthesis, structure and preliminary complexation behaviour of macrocyclic thioureas and ureas
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1267-1269
- https://doi.org/10.1039/c39930001267
Abstract
Tricyclic ligands incorporating bis(thiourea) subunits may be prepared from the corresponding monocyclic [18]- and [24]-ring N4O2 and N4O4 polyaza-compounds and adopt a trans-conformation in the free ligand; an unusual trisilver(I) complex is formed with the N4O2-derived ligand with bridging nitrate groups in which the thiourea groups are cis-oriented.Keywords
This publication has 0 references indexed in Scilit: