1‐Phospha‐1,2,3‐butatriene
- 1 November 1986
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 25 (11) , 1003-1004
- https://doi.org/10.1002/anie.198610031
Abstract
The first phosphacumulenes of type 1 have been synthesized from dichloro(2,4,6‐tri‐tert‐butylphenyl)phosphane and lithioallenes. According to an X‐ray structure analysis, the unit in 1a, R′ = R″ = Ph, is linear. In the case of 1b, with Me and SiMe3 as substituents (R′, R″), the expected E/Z isomer could be isolated. equation imageKeywords
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