Solid solubility in the NaF-LiF system

Abstract
The limits of solid solubility for the NaF-LiF system were determined by the x-ray diffraction method to be 065±002 mole% NaF in LiF, and 45±02 mole% LiF in NaF. The measurements indicate that the Na ion enters the LiF lattice substitutionally, while the Li ion is accepted interstitially as well as substitutionally by the NaF lattice.

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