Three-fold Interpenetrating Diamondoid Frameworks with π–π Stacking of Alternate Coordinated and Uncoordinated Ligands: Crystal Structures of Copper(I) Coordination Compounds, [Cu(DMTPN)2]X(DMTPN)(thf) (DMTPN = 2,5-Dimethylterephthalonitrile; X = BF4,ClO4)
- 1 May 1996
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 25 (5) , 349-350
- https://doi.org/10.1246/cl.1996.349
Abstract
Two novel coordination polymer compounds, [Cu(DMTPN)2]X(DMTPN)(thf) (DMTPN = 2,5-dimethylterephthalonitrile, X = BF4 (l) and ClO4 (2)) are prepared and characterized by single crystal X-ray analysis; both are isostructural and have three-fold interpenetrated diamondoid structure with π–π stacking column of alternate coordinated and uncoordinated DMTPN.This publication has 11 references indexed in Scilit:
- Coexistence of one- and three-dimensional Fermi surfaces and heavy cyclotron mass in the molecular conductor (DMe-DCNQICuPhysical Review B, 1994
- The organic metal (Me2-DCNQI)2Cu: Dramatic changes in solid-state properties and crystal structure due to secondary deuterium effectsJournal of the American Chemical Society, 1993
- Complex polymeric cations of copper(I) with graphite- and diamond-related lattices; crystal structures of poly-tris(.mu.-2,5-dimethylpyrazine)dicopper(I) hexafluorophosphate and poly-bis(.mu.-2,5-dimethylpyrazine)copper(I) hexafluorophosphateInorganic Chemistry, 1993
- Sevenfold diamond structure and conductivity of copper dicyanoquinonediimines Cu(DCNQI)2Advanced Materials, 1991
- Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2Journal of the American Chemical Society, 1990
- Infinite polymeric frameworks consisting of three dimensionally linked rod-like segmentsJournal of the American Chemical Society, 1989
- Synthesis and structure of new anion radical salts from DCNQIsSynthetic Metals, 1988
- The organic π-electron metal system with interaction through mixed-valence metal cation: Electronic and structural properties of radical salts of dicyano-quinodiimine, (DMe-DCNQI)2Cu and (MeCl-DCNQI)2CuSolid State Communications, 1987
- A Radical Anion Salt of 2,5‐Dimethyl‐N,N′‐dicyanoquinonediimine with Extremely High Electrical ConductivityAngewandte Chemie International Edition in English, 1986
- The Crystal Structure of Bis(adiponitrilo)copper(I) NitrateBulletin of the Chemical Society of Japan, 1959