Solvatochromism of a typical merocyanine dye. Further investigations
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions
- Vol. 89 (1) , 55-57
- https://doi.org/10.1039/ft9938900055
Abstract
This paper reports on the solvatochromism of a new typical merocyanine dye of stilbazolium betaine. Solvatochromic absorption and fluorescence energy shifts of 2-(4-hydroxystyryl)-1-methylpyridinium betaine {4-[2-(1-methyl-2-pyridinio)vinyl]phenolate}, M, in 10 polar solvents are 15.0 and 6.0 kcal mol–1(1 cal = 4.184), respectively. Absorption and fluorescence energies vary rectilinearly with Dimroth–Reichardt's empirical solvent polarity parameter, ET(30). Depending on the nature of solvent, the non-specific dipole–dipole interactions and specific hydrogen bonding are described on the basis of the least-squares fitting of the absorption and fluorescence energies to multilinear equations with Taft's π*(solvent polarity) and α(hydrogen bond donor ability) parameters.Keywords
This publication has 0 references indexed in Scilit: