Solid-state photo-polymerization of unsaturated organic cations in layer perovskite halide salts
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 921-922
- https://doi.org/10.1039/c39810000921
Abstract
U.v. and X-ray irradiation causes polymerization of amino-diacetylene cations R1NH3 + and H3NR2NH3 2+ where R1= ClCH2CC–CCCH2– and R2=(–CH2CO2CH2CC–)2 in the solid salts (R1NH3)2CdCl4 and (H3NR2NH3)CdCl4 with he layer perovskite structure; under the same conditions tetrachlorocadmate salts (RNH3)2CdCl4(R = CH2 CHCH2– and CHCCH2–) do not react.Keywords
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