Über die Umsetzung von Alkylaziden mit Nitrosylchlorid und Antimon(V)-chlorid / The Reaction of Alkyl Azides with Nitrosyl Chloride and Antimony(V) Chloride
Open Access
- 1 June 1975
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 30 (5-6) , 295-298
- https://doi.org/10.1515/znb-1975-5-601
Abstract
Methyl azide reacts with nitrosyl hexachloroantimonate(V) according to the conditions to yield nitrogen, dinitrogen oxide and methyl chloride or N-methylmethylenimonium hexachloroantimonate(V) (1). Independant of the conditions ethyl or isopropyl azide give 1:1-compounds of the azides with antimony(V) chloride and ethylidene or isopropylideneimonium hexachloroantimonate(V) (2) or (8).Keywords
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