A novel asymmetric desymmetrisation of meso-cyclopentane-1,2-diol via diasteroselective β-elimination of chiral α-arylsulfinyl acetals
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 1345-1346
- https://doi.org/10.1039/c39940001345
Abstract
meso-Cyclopentane-1,2-diol was differentiated via diasteroselective C–O bond fission of the acetal utilising the anion stabilised by a neighbouring chiral sulfinyl group to provide the chiral alcohol.Keywords
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