Formation of molecular hydrogen complexes of iron by the reversible protonation of iron dihydrides with alcohols

Abstract
Reversible protonation of cis-FeH2(PP)2[PP = R2PCH2CH2PR2] complexes by ethanol produces the η2-co-ordinated molecular hydrogen complexes trans-FeH(H2)(PP)2 + which readily undergo substitution with loss of H2.

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