Laser Ablation-Molecular Beam Method: A Versatile Diagnosis for the Reactions of Metal Ions with Molecules in the Gas Phase. Dimanganese Decacarbonyl
- 5 November 1988
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 17 (11) , 1865-1868
- https://doi.org/10.1246/cl.1988.1865
Abstract
Intense laser light was focussed on the surface of a metal substrate (Nb or Cu) in vacuum, and a molecular beam of Mn2(CO)10 was injected nearby. Product ions resulting from the reaction of substrate metal ions or electrons with Mn2(CO)10 were analyzed by mass-spectroscopy. This method provides a simple and versatile diagnosis for the reactions of metal ions and/or electrons with molecules in the gas phase.Keywords
This publication has 14 references indexed in Scilit:
- Gas-phase transition metal ion chemistry: the reactivity and specificity of atomic iron(I), chromium(I) and molybdenum(I) ions with alcoholsOrganometallics, 1986
- Heteronuclear transition-metal cluster ions in the gas phase. Photodissociation and reactivity of vanadium-iron cluster ion (VFe+)Journal of the American Chemical Society, 1985
- Pulsed laser evaporation and ionization of solid metal targets. Implications for studying the gas-phase reactions of laser-generated atoms and ionsThe Journal of Physical Chemistry, 1985
- Mechanism of the reaction of gas-phase iron ions with neutral olefinsJournal of the American Chemical Society, 1984
- Gas-phase chemistry of atomic metal cations with metal carbonyls. A novel route to mixed-metal clustersThe Journal of Physical Chemistry, 1982
- Gas-phase chemistry of copper(1+) with alkyl chloridesJournal of the American Chemical Society, 1980
- Laser ionization source for ion cyclotron resonance spectroscopy. Application to atomic metal ion chemistryInternational Journal of Mass Spectrometry and Ion Physics, 1980
- Coordination chemistry of copper(I) in the gas phaseJournal of the American Chemical Society, 1979
- Photodissociation of molecular beams. Cleavage of metal-metal bonds in rhenium and manganese decacarbonylJournal of the American Chemical Society, 1978
- Reactions of transition metal ions with alkyl halides and alcohols in the gas phase: evidence for metal insertion and .beta.-hydrogen atom shiftJournal of the American Chemical Society, 1976