The hydrogenation and isomerisation of unsaturated tertiary phosphine complexes of rhodium(I)
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 17,p. 1115
- https://doi.org/10.1039/c29700001115
Abstract
The hydrogenation (a two-step process) and isomerisation of RhCl(CO)[Ph2P(CH2)n·CHCH2]2, where n= 0, 1, 2, or 3, are controlled by the steric requirements of the ligand whose interactions are most favourable when n= 2.Keywords
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