Asymmetric ring transformation of meso-7-substituted bicyclo[3.3.0]octanones into chiral bicyclo[3.2.1]octene derivatives
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1482-1483
- https://doi.org/10.1039/c39920001482
Abstract
Asymmetric ring transformation of meso-7-(2-oxoalkyl)bicyclo[3.3.0]octan-3-ones into chiral bicyclo[3.2.1]oct-2-ene derivatives is accomplished by treatment with chiral cyclic (six- or seven-membered ring) 1,2-diols–BF3–Et2O.Keywords
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