Analytic form of the correlation energy of the uniform electron gas
- 26 January 2009
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 79 (1) , 014103
- https://doi.org/10.1103/physreva.79.014103
Abstract
An expression for the correlation energy density of the uniform electron gas is derived based on the adiabatic connection method. It covers with a single form the transition between high-density and low-density regions in the range , parsing the entire spin-polarization range . The pair-correlation function used to generate the result has been used previously to describe mainly finite systems. We argue that the universality implied by the short-wavelength hypothesis goes both ways, and a model that works well for finite systems may be adapted to describe the uniform electron gas as well.
Keywords
This publication has 32 references indexed in Scilit:
- Climbing the Density Functional Ladder: Nonempirical Meta–Generalized Gradient Approximation Designed for Molecules and SolidsPhysical Review Letters, 2003
- Accurate Density Functional with Correct Formal Properties: A Step Beyond the Generalized Gradient ApproximationPhysical Review Letters, 1999
- Generalized Gradient Approximation Made SimplePhysical Review Letters, 1996
- Nonlocal correlation functional involving the Laplacian of the density (Chem. Phys. Letters 230 (1994) 419)Chemical Physics Letters, 1995
- Nonlocal correlation functional involving the Laplacian of the densityChemical Physics Letters, 1994
- Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlationPhysical Review B, 1992
- Exchange holes in inhomogeneous systems: A coordinate-space modelPhysical Review A, 1989
- Correlation energy of an inhomogeneous electron gas: A coordinate-space modelThe Journal of Chemical Physics, 1988
- Development of the Colle-Salvetti correlation-energy formula into a functional of the electron densityPhysical Review B, 1988
- Self-Consistent Equations Including Exchange and Correlation EffectsPhysical Review B, 1965