A study of the ion [Ta2OF10]2−
- 1 June 1978
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 56 (11) , 1545-1548
- https://doi.org/10.1139/v78-250
Abstract
Hydrolysis of (Et4N)[TaF6] with Et4NOH in organic medium gives (Et4N)2[Ta2OF10]. The Ta—O—Ta infrared and Raman frequencies reflect the linearity of the bridge, in agreement with a previous X-ray study. The 19F nmr spectrum is of the type AA′E4E4′. Chemical shifts are compared with other pseudo-octahedral species of tantalum with formula [TaF5L].Keywords
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