Synthesis of bis(η-pentamethylcyclopentadienyl)rhenium hydride and its photochemical conversion into decamethylrhenocene
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 967-968
- https://doi.org/10.1039/c39850000967
Abstract
Cocondensation of rhenium vapour with 1,2,3,4,5-pentamethylcyclopentadiene gives bis(η-pentamethylcyclopentadienyl)rhenium hydride; photolysis of the hydride yields monomeric bis(η-pentamethylcyclopentadienyl)rhenium, and reduction of the latter gives a stable anion which may be readily converted into bis(η-pentamethylcyclopentadienyl)methylrhenium.Keywords
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