Reaction of O-benzyl-N-methylenehydroxylamine with organolithium compounds, a CH2+–NH+synthetic equivalent
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 305-306
- https://doi.org/10.1039/c39870000305
Abstract
Lithium carbanions add sequentially to O-benzyl-N-methylenehydroxylamine (1), first at eh electrophioic carbon and subsequently, at higher temperature, on the nitrogen with concomitant loss of the benzyloxy group, resulting in a CH2 +–NH+ synthetic equivalent, the amines (4) being produced.Keywords
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