Raman Effect in Mixtures of Some Esters with Phenol and Alcohols: Hydrogen Bond Formation
- 1 March 1957
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 26 (3) , 601-603
- https://doi.org/10.1063/1.1743353
Abstract
The variations in the frequencies of some of the Raman lines of methyl and ethyl benzoates and ethyl cinnamate, in phenol and methyl alcohol, have been recorded for different concentrations. In all the three cases the C=O frequencies at 1724, 1719, and 1711 cm‐1 are lowered as a result of hydrogen bond formation. This reduction is always accompanied by an increase in the frequencies assigned to the C–O link, which is adjacent to the C=O link. Besides these, variations in other frequencies are reported and explained.Keywords
This publication has 4 references indexed in Scilit:
- Assignment of the raman frequencies of methyl and ethyl benzoates and ethyl cinnamateProceedings of the Indian Academy of Sciences - Section A, 1955
- Study of Chelation through Raman EffectThe Journal of Chemical Physics, 1955
- Raman effect in mixtures of benzaldehyde with alcohols and phenolProceedings of the Indian Academy of Sciences - Section A, 1953
- Raman effect in mixtures of acetone with alcoholsProceedings of the Indian Academy of Sciences - Section A, 1953