A reinvestigation of the enthalpies of reaction of silicon, germanium, and tin tetrahalides with pyridine and isoquinoline
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 3327-3330
- https://doi.org/10.1039/j19700003327
Abstract
Enthalpies of formation of crystalline MX4,2L complexes (where M = Si, Ge, or Sn; L = pyridine or isoquinoline; X = F, Cl, or Br, except X = Cl only when M = Sn) have been redetermined with a more sensitive calorimeter and improved techniques to exclude water impurity. Contrary to previous results, values do not vary greatly in each series of related adducts, except for the order GeF4,2L > SiF4,2L.Keywords
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