Neighbouring group participation in the cleavage of some steroidal acetoxy-epoxides
- 1 January 1976
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 23,p. 2508-2516
- https://doi.org/10.1039/p19760002508
Abstract
Participation of a vicinal trans-axial acetoxy-group in the boron trifluoride-catalysed cleavage of steroidal epoxides, resulting in some cases in overall diequatorial opening of the oxiran ring, is described.Keywords
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