Monoalkylation of primary aliphatic amines via N-alkyl-N-(alkylthiomethyl) ammonium chlorides. Evidence for the formation of stable N-methylenealkylamines
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 427-428
- https://doi.org/10.1039/c39840000427
Abstract
Monomeric N-methylenealkylamines (3), formed from N-alkyl-N-(alkylthiomethyl)ammonium chlorides (5) are stable at –60 °C and may be trapped with organometallic reagents to provide the N,N-dialkylamines (8).Keywords
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