η-Arene complexes of scandium(0) and scandium(II)
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1372-1373
- https://doi.org/10.1039/c39910001372
Abstract
Cocondensation of scandium vapour with 1,3,5-tri-tert-butylbenzene affords the first example of a scandium(0) complex, the sandwich compound bis(η-1,3,5-tri-tert-butylbenzene)scandium; ESR and UV studies also the reveal the presence of a second compound from this reaction, formulated as a similarly unique example of scandium(II) arising from activation of one of the methyl groups of a tert-butyl ring substituent.Keywords
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