Rhodium-Catalyzed Carbonylative [3+2+1] Cycloaddition Reaction: Catalytic Formation of Bicyclic Cyclohexenones from Trienes and Carbon Monoxide
- 12 February 2004
- journal article
- editorial
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (9) , 2714-2715
- https://doi.org/10.1021/ja039301+
Abstract
The rhodium-catalyzed carbonylative [3+2+1] cycloaddition of trienes into bicyclohexenones has been developed. The carbonylated cycloaddition products have a high regioselectivity. This catalytic system tolerates functionalities including ether, sulfonamide, and ester.Keywords
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