Diels–Alder reactions in hydrophobic cavities: a quantitative correlation with solvophobicity and rate enhancements by macrocycles
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1787-1789
- https://doi.org/10.1039/c39860001787
Abstract
Based on the reaction of cyclopentadiene with diethyl fumarate a linear correlation of log k vs. solvophobicity parameters is reported as well as saturation kinetics showing up to 70-fold rate increase by complexation in β-cyclodextrin.Keywords
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