Comments on Quartic Centrifugal Distortion Constants for Asymmetric Top Molecules

Abstract
Explicit relations between the spectroscopic constants, A͂ , B͂ , C͂, ⊿J,⊿JK, ⊿K, δJ,and δK, obtained by the application of the various reduction procedures of the effective rotational Hamil­tonian are given in matrix formulation. Watson’s reduction procedures for the three different axis representations Ir, IIr, and IIIr have been considered as well as the reduction making R͂5 = 0, in­stead of R͂6 = 0. The ambiguity in the determination of the τ’s arising from the use of planarity conditions is discussed in relation to the τ defect.