THE PHOTOOXIDATION OF AZOMETHANE. II
- 1 September 1959
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 37 (9) , 1456-1461
- https://doi.org/10.1139/v59-214
Abstract
In a further investigation of the photooxidation of azomethane it was found that the yields of all products depend on the fractional conversion in a manner which suggests that some inhibitor is produced. Products from experiments at lower pressures of azomethane are obtained in yields appropriate to the higher conversions. Only very small changes in yields are observed for relatively large variations in light intensity. The implications of these facts to the mechanism of the photooxidation are discussed.Keywords
This publication has 8 references indexed in Scilit:
- A Study of the Methyl-Oxygen and the Methyl-Nitric Oxide Reactions by Flash Photolysis1Journal of the American Chemical Society, 1959
- The Photoöxidation of Diethyl Ketone1Journal of the American Chemical Society, 1957
- The reaction of methyl radicals with oxygen and comparison with other third-order reactionsTransactions of the Faraday Society, 1957
- THE PHOTO-OXIDATION OF AZOMETHANECanadian Journal of Chemistry, 1955
- Oxidation of the Radicals Produced in Acetone PhotolysisJournal of the American Chemical Society, 1953
- The Photochemical Decomposition of AzomethaneThe Journal of Chemical Physics, 1953
- The Oxidation of Free Methyl RadicalsJournal of the American Chemical Society, 1951
- Spectrophotometric Method for Determining FormaldehydeIndustrial & Engineering Chemistry Analytical Edition, 1945