Observation of a Continuum in Enhanced Raman Scattering from a Metal-Solution Interface
- 2 July 1979
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 43 (1) , 71-75
- https://doi.org/10.1103/physrevlett.43.71
Abstract
A background continuum in the Raman spectrum of adsorbed molecules at a silverelectrolyte interface is observed experimentally. This background continuum is potential dependent on the Stokes and anti-Strokes of the spectrum and fits a Fermi distribution function on the anti-Stokes side of the spectrum. The continuum is interpreted in terms of radiative recombination of adsorbed molecular ions produced by photoionization.Keywords
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