Some substitution reactions of amminediethylenetriaminepalladium(II) salts in aqueous solution
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2669-2672
- https://doi.org/10.1039/j19690002669
Abstract
The rate of aquation and chloride substitution reactions of Pd dien NH3 2+ have been studied in acid aqueous solution. The replacement of NH3 by Cl– follows the expected two-term rate law but is preceded by rapid side reactions involving the opening of one ring of the chelated ligand.Keywords
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