Photo-oxidation of [Ru(CN)6]4–, [Mo(CN)8]4–, and [W(CN)8]4–in chloroform to give, respectively, [Ru(CN)6]3–, [Mo(CN)8]3–, and [W(CN)8]3–
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 187-188
- https://doi.org/10.1039/c39790000187
Abstract
Upon charge-transfer excitation (λirrad= 228 nm)[Ru(CN)6]4–, [Mo(CN)8]4–, and [W(CN)8]4–, dissolved in CHCl3, are photo-oxidized to [Ru(CN)6]3–(ϕ= 0·49), [Mo(CN)8]3–(ϕ= 0·40), and [W(CN)8]3–(ϕ= 0·37).Keywords
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