The role of neighbouring group participation in TTF-mediated ‘radical-polar crossover’ reactions: trapping of aliphatic radicals by TTF+·
- 22 March 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 627-628
- https://doi.org/10.1039/b000786m
Abstract
Trapping of secondary alkyl radicals with tetrathiafulvalenium tetrafluoroborate (TTF+·BF4 −) leads to S-alkyltetrathiafulvalenium tetrafluoroborate salts; the solvolysis of such salts is critically dependent on the presence of appropriately sited neighbouring groups.Keywords
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