Amides of rhodium(I) and ruthenium(II), [Rh(NR2)(PPh3)2] and [RuH(NR2)(PPh3)2](R = Me3Si): novel low co-ordination number d 8 and d 6 metal complexes
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 843-844
- https://doi.org/10.1039/c39790000843
Abstract
Reaction of LiNR2(R = Me3Si) with [RhCl(PPh3)3] or [RuH(Cl)(PPh3)3] in tetrahydrofuran (thf) yields the cyclohexane-soluble, monomeric, diamagnetic amides [Rh(NR2)(PPh3)2] or [RuH(NR2)(PPh3)2], which on heating decompose with elimination of HN(SiMe3)2; the RuII compound has equivalent P atoms, but inequivalent SiMe3 environments.Keywords
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