The Free-Radical Chemistry of Fluoroketones. II. Reaction with Unsaturated Compounds
- 1 October 1967
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 1 (6) , 1011-1023
- https://doi.org/10.1080/10601326708053754
Abstract
Free radicals induce two principal types of interaction between fluoro-ketones and olefins, both of which lead to polymeric products. Copolym-erization of the fluoroketone through its carbonyl group leads to poly-ethers. Hydrogen abstraction, presumed to be largely intramolecular, also occurs to give highly branched polymers with fluoroalcohol groups at terminal positions on the branches.Keywords
This publication has 5 references indexed in Scilit:
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- Hydrogen Bonding in Fluoro AlcoholsJournal of the American Chemical Society, 1964
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- Synthesis of Polyfluoroöxetanes by Photoinitiated Addition of Fluorocarbonyl Compounds to FluoroölefinsJournal of the American Chemical Society, 1962
- The reaction of hexafluoroacetone with olefinsRussian Chemical Bulletin, 1962