Chemical Correlations of α-Santonin with (+)-Junenol and Acolamone
- 1 November 1976
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 49 (11) , 3145-3147
- https://doi.org/10.1246/bcsj.49.3145
Abstract
The chemical transformation of the acetoxy ketone (5), which has previously been obtained from α-santonin, to (+)-junenol (1) and acolamone (3) has been carried out. In addition, isojunenol (2) was also derived from 5 via the trisubstituted olefin (9) which was obtained as the main product from the α- and β-oriented mesylates (8 and 11) on treatment with NaI in HMPA.Keywords
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