Relative scale of free energy of transfer of anions from water to 1,2-dichloroethane
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 76, 1663-1668
- https://doi.org/10.1039/f19807601663
Abstract
Partition data for quaternary ammonium salts in the 1,2-dichloroethane + water system have been extrapolated to zero concentration to yield the true partition coefficients, P, of the electrolytes. The values of P were used to evaluate a relative scale of free energy of transfer of some anions from the aqueous phase to the organic phase. The values for transfer decrease in the order: F–, Cl–, Br–, NO– 3, ClO– 3, I–, SCN–, ClO– 4, Ph4B–.Keywords
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