Active catalysts prepared using a vanadium-containing oligosilsesquioxane for selective photo-assisted oxidation of methane into methanal
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 133-134
- https://doi.org/10.1039/a707173f
Abstract
Catalysts of characteristic pore structure derived from silica-supported vanadium-containing silsesquioxane show excellent activity towards the selective photo-assisted catalytic oxidation of methane into methanal (at 493 K, 139 µmol h–1, TON ca. 9 h–1, selectivity 81%), indicating its potent abilities as an excellent precursor for porous oxide catalysts.Keywords
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