Methoxy-group migration in the hydrolysis of the 4-nitrobenzene-p-sulphonates of methyl β-D-xylopyranoside and methyl β-D-glucopyranoside
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 10,p. 558-559
- https://doi.org/10.1039/c29690000558
Abstract
One of the products of hydrolysis of methyl 4-O-nitrobenzene-p-sulphonyl-β-D-xylopyranoside, at pH 5, is 4-O-methyl-L-arabinose, while the corresponding β-D-glucopyranoside yields both 4-O-methyl-D-galactose and methyl α-L-altrofuranoside as products.Keywords
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