Generation and Aldehyde Addition of a Zinc Carbenoid Substituted by Fluorine
- 1 September 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (09) , 831-832
- https://doi.org/10.1055/s-1996-5623
Abstract
The fluorinated carbenoid reagent XZnCFBr2 was prepared by treatment of tribromofluoromethane with Et2Zn in DMF at -60 °C and allowed to react with aldehydes RCHO chemoselectively to give fluoroalcohols RCH(OH)CFBr2 (1).Keywords
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