Enantioselective ortho-hydroxyalkylation of phenols promoted by chiral alkoxyaluminium chlorides
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1210-1211
- https://doi.org/10.1039/c39830001210
Abstract
The asymmetric ortho-specific hydroxyalkylation of phenols with trichloroacetaldehyde in the presence of chiral alkoxyaluminium chlorides gives rise to optically active 2-(2,2,2-trichloro-1-hydroxyethyl) phenols, with good optical yields.Keywords
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