Synthesis of quinolines via ruthenium-catalysed amine exchange reaction between anilines and trialkylamines
- 18 September 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 19,p. 1885-1886
- https://doi.org/10.1039/b005966h
Abstract
Anilines react with an array of trialkylamines in the presence of a catalytic amount of RuCl3·nH2O and bis(diphenylphosphino)methane together with SnCl2·2H2O and hex-1-ene as hydrogen acceptor in dioxane at 180 °C to afford the corresponding 2,3-disubstituted quinolines in moderate to good yields.Keywords
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