Bridging acetylene complexes of nickel and platinum; X-ray crystal structure of [Pt3(Et3P)4(PhC2Ph)2]
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 930-931
- https://doi.org/10.1039/c39770000930
Abstract
Di- and tri-platinum, and di-nickel acetylene complexes have been prepared, e.g.[Pt2{µ2(η2-PhC2Ph)}-(η2-PhC2Ph)(Ph3P)2], [Ni2{µ2(η2-Me3SiC2SiMe3)}(cod)2], and [Pt3{µ2(η2-PhC2Ph)}2(Et3P)4]; a single crystal X-ray diffraction study of the latter revealed a Pt·Pt·Pt sequence bridged transversely by two diphenylacetylene ligands.Keywords
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