Far-infrared composite-medium study of sintered La2NiO4 and La1.85Sr0.15CuO4y

Abstract
The infrared and far-infrared properties of sintered La2NiO4 and La1.85Sr0.15CuO4y are modeled accurately within the effective-medium approximation. The electrodynamic properties of La1.85Sr0.15CuO4y grains are highly anisotropic with the strong 0.5-eV electronic transition polarized along the low-conductivity crystal direction. The apparent superconducting gap frequency for the sintered material depends crucially on the grain geometry. Our experimental data are fit with needlelike crystallites and 2ΔkBTc=2.6.