Ti(II)-Mediated Allenyne Cyclization as a New Tool for Generation of Chiral Organotitanium Compounds. Asymmetric Generation of Cyclic Allyltitanium Reagents with No Chiral Auxiliary
- 1 November 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 119 (46) , 11295-11305
- https://doi.org/10.1021/ja972045e
Abstract
No abstract availableKeywords
This publication has 36 references indexed in Scilit:
- Asymmetric Photocycloadditions with an Optically Active Allenylsilane: Trimethylsilyl as a Removable Stereocontrolling Group for the Enantioselective Synthesis of exo-MethylenecyclobutanesJournal of the American Chemical Society, 1997
- Intramolecular cyclization of conjugated diene and acetylene with (η2-propene)Ti(O-i-Pr)2. Generation and reaction of titanabicycles having an allyltitanium moietyTetrahedron Letters, 1996
- A Novel Tandem Cyclization of 2,7- or 2,8-Bis-Unsaturated Esters Mediated by (η2-Propene)TiX2 (X = Cl or O-i-Pr). A Facile Construction of Bicyclo[3.3.0]octane, -[4.3.0]nonane, and -[3.1.0]hexane SkeletonsJournal of the American Chemical Society, 1996
- Selective Reaction of Aldehydes with Bicyclic Titanacyclopentadienes or Titanacyclopentenes Prepared in Situ from 1,6- or 1,7-Diynes or Enynes and (η2-Propene)Ti(O-i-Pr)2The Journal of Organic Chemistry, 1996
- Intramolecular Nucleophilic Acyl Substitution Reaction of 3,4-Alkadienyl Carbonates Mediated by Ti(O-i-Pr)4/2 i-PrMgCl Reagent. Efficient Synthesis of Optically Active β,γ-Unsaturated Esters with an α-SubstituentThe Journal of Organic Chemistry, 1996
- Synthetic application of titanabicycles generated from 1,6- or 1,7-dienes, enynes, and diynes and (ν2-propene)Ti(O-i-Pr)2Tetrahedron Letters, 1995
- New, Efficient Method for the Synthesis of Allyltitanium Compounds from Allyl Halides or Allyl Alcohol Derivatives via Oxidative Addition. A Highly Efficient and Practical Synthesis of Homoallyl AlcoholsJournal of the American Chemical Society, 1995
- Regio- and stereoselective formation and isomerization of 1,3-cyclohexadienes catalyzed by titanium aryloxide compoundsJournal of the American Chemical Society, 1993
- Novel allene-acetylene cross-condensation catalyzed by palladium complexesJournal of the American Chemical Society, 1990
- Electrophilic addition to allenic derivatives: selectivity, regio- and stereochemistry and mechanismsChemical Reviews, 1983