Aliphatic Nitroso-compounds. Part 1. Reaction with Diazomethane. A New Group of Nitrones
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- No. 7,p. 1073-1079
- https://doi.org/10.1039/j3969001073a
Abstract
Nitrosoalkanes react quantitatively with diazomethane to yield a new series of nitrones, unsubstituted at the α-carbon. Their adducts with several 1,3-dipolarophiles are described. N-Methylenemesitylarnine N-oxide slowly undergoes dimerisation and oxidation to a yellow ethylenedi-imine di-N-oxide.Keywords
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