Crystal structure of [Me3NCH2Ph][Fe4(CO)13H]. A ‘butterfly’ metal cluster with an unusually bonded carbonyl group
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 919-920
- https://doi.org/10.1039/c39760000919
Abstract
A single-crystal X-ray analysis has shown the [Fe4(CO)13H]– anion to contain a butterfly arrangement of metal atoms; twelve carbonyl groups are terminally bonded, three to each iron atom, whereas the thirteenth carbonyl group interacts with all the four iron atoms and behaves as a four-electron ligand.Keywords
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