A versatile and stereocontrolled synthesis of quinolizidines and indolizidines using trialkylsilyl trifluoromethanesulphonate: total synthesis of (±)-tylophorine
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1159-1161
- https://doi.org/10.1039/c39850001159
Abstract
Quinolizidines and indolizidines were synthesised by reaction of α,β-unsaturated enamide esters with trialkylsilyl trifluoromethanesulphonate and triethylamine in dichloromethane; a short total synthesis of (±)-tylophorine (16) was achieved via annelation.Keywords
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